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Abstract On the main sequence, the asteroseismic small frequency separationδν₀₂between radial and quadrupolep-modes is customarily interpreted to be a direct diagnostic of internal structure. Such an interpretation is based on a well-known integral estimator relatingδν₀₂to a radially averaged sound-speed gradient. However, this estimator fails, catastrophically, when evaluated on structural models of red giants: their small separations must therefore be interpreted differently. We derive a single expression that both reduces to the classical estimator when applied to main-sequence stellar models and reproduces the qualitative features of the small separation for stellar models of very evolved red giants. This expression indicates that the small separations of red giants scale primarily with their global seismic properties as $\delta {\nu }_{02}\propto \Delta {\nu }^2/{\nu }_{\max }$, rather than being in any way sensitive to their internal structure. Departures from this asymptotic behavior, during the transition from the main-sequence to red giant regimes, have been recently reported in open-cluster Christensen–Dalsgaard (C-D) diagrams from K2 mission data. Investigating them in detail, we demonstrate that they occur when the convective envelope boundary passes a specific acoustic distance—roughly one-third of a wavelength at ${\nu }_{\max }$—from the center of the star, at which point radial modes become maximally sensitive to the position of the boundary. The shape of the corresponding features onϵ_pand C-D (orr₀₂) diagrams may be useful in constraining the nature of convective boundary mixing in the context of undershooting beneath a convective envelope.